We review the cross sections for low-energy π − γ reactions in the framework of chiral perturbation theory. Charged pion Compton scattering, π − γ → π − γ, is considered up to one-loop order where the pion's internal structure enters through the difference of the electric and magnetic pion polarizability, α π − β π . The ongoing COMPASS experiment aims at measuring this important structure constant with high statistics using the Primakoff effect. In the same way, the reaction π − γ → π − π 0 serves as a test of the QCD chiral anomaly (via the γ3π-coupling constant F γ3π ). Furthermore, we calculate the total cross sections for neutral and charged pion-pair production, π − γ → π − π 0 π 0 and π − γ → π − π + π − , which are governed by the chiral ππ-interaction. Finally, we investigate the radiative (correction) process π − γ → π − γγ and calculate the corresponding twophoton mass spectrum. This information will be useful for analyzing the π − Primakoff scattering events with photons in the final state.