Radiation effects in hydrolysed CaF2, SrF2 and BaF2

Peña, J. I.; Alonso, Pablo J.; Alcalá, R.

doi:10.1016/0022-3697(88)90078-9

Cited by 13 publications

(1 citation statement)

References 16 publications

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“…Various paramagnetic centres introduced, for EPR studies, into cubic fluorite type crystal structures (CaF 2 , CdF 2 , SrF 2 , BaF 2 , SrCl 2 ) substitute divalent host metals (such as Cu 2+ , Ag 2+ , Ni + , Cr 2+ , Cr 3+ [1][2][3][4][5][6][7][8]; Sc 2+ , La 2+ [9]; atomic hydrogen H 0 [10,11]) or occupy anionic sites (like O − or OH − ) [12,13]. The transition metal ion behaviour in fluorite structures prior to 1980 has been reviewed in [14].…”

Section: Introductionmentioning

confidence: 99%

Off-centre dynamic Jahn-Teller effect studied by electron spin relaxation of Cu²⁺ions in SrF₂crystal

Hoffmann

Уланов

2000

J. Phys.: Condens. Matter

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Temperature cw-EPR and pulsed EPR electron spin echo experiments were performed for a low concentration of Cu2+ ions in cubic SrF2 crystals. The well resolved EPR spectrum at low temperatures (below 30 K) with parameters g = 2.493, g = 2.083, A = 121, A = 8.7, A (19 F) = 135, A (19 F) = 33.0 (A -values in 10-4 cm-1 ) is transformed continuously into a single broad line above 225 K on heating, due to the g -factor shift and EPR line broadening. These data along with the angular variation EPR data are described in terms of a pseudo-Jahn-Teller effect of (T2g +A2u ) (a1g +eg +t1u ) type producing six off-centre positions of the Cu2+ ion in the fluorine cube. Above 30 K a two-step averaging g -factor process occurs and is governed by vibronic dynamics between potential wells of the off-centre positions. This dynamics governs the electron spin relaxation in the whole temperature range. The electron spin-lattice relaxation rate 1/T 1 grows rapidly by six orders of magnitude in the temperature range 30-100 K and is determined by the Orbach-type process with excitations to two excited vibronic levels of energy 83 and 174 cm-1 . For higher temperatures the relaxation is dominated by overbarrier jumps leading to the isotropic EPR spectrum above 225 K. The phase memory time TM has the rigid lattice value 3.5 µs determined by nuclear spectral diffusion and its temperature variation is governed by the vibronic dynamics indicating that the excitations between vibronic levels produce a dephasing of the electron spin precessional motion.

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