We measured the degree of linear polarization of Comet C/2020 S3 (Erasmus) on November 13, 20, 22, and 23, 2020, while the comet was observed at large phase angles, α = 62.6° – 66.6°. On the first two epochs, the polarization closely matched what was previously observed in Comet C/1989×1 (Austin). On the third epoch, the polarization was found to rise slightly, and on the latest epoch, it rose significantly, exceeding that of Comet Austin. On the last observation, the polarization of Comet Erasmus appears to be more consistent with what was previously seen in Comet C/1996 B2 (Hyakutake) at a similar phase angle. While such short-term transient behavior has been seen previously, Comets Austin and Hyakutake belong to two different classes in classifications based on the amplitude of their positive polarization Pmax and, hence, Comet Erasmus revealed a transition from the class of low Pmax comets to that of high Pmax comets within only a few days. Polarization images and modeling suggest that the transition occurred due to a decrease in the relative abundance of Mg-rich silicate particles in the inner coma by 1/3, revealing a qualitative change in emanations of dust particles from the Erasmus nucleus.