Resistively Detected Nuclear Magnetic Resonance (RD-NMR) has been used to investigate a twosubband electron system in a regime where quantum Hall pseudo-spin ferromagnetic (QHPF) states are prominently developed. It reveals that the easy-axis QHPF state around the total filling factor ν = 4 can be detected by the RD-NMR measurement. Approaching one of the Landau level (LL) crossing points, the RD-NMR signal strength and the nuclear spin relaxation rate 1/T1 enhance significantly, a signature of low energy spin excitations. However, the RD-NMR signal at another identical LL crossing point is surprisingly missing which presents a puzzle.PACS numbers: 73.43. Nq, 71.30.+h, 72.20.My The multi-component electron systems have been continuously drawing intensive research interest because of its novel ground states and excitations [1]. In experimental systems, different Landau levels (LLs) can be tuned to cross by varying gate voltage, charge density, magnetic field or the magnetic field tilted angle to the sample. Electron-electron correlations become particularly prominent when two or more sets of LLs with different layer, subband, valley, spin, or Landau level indices are brought into degeneracy [1,2,3,4,5,6,7,8]. Recent experiments in single quantum well with two subbands occupied systems [5,6], showed evidence of the formation of quantum Hall pseudospin ferromagnets (QHPFs) due to the interactions of the two subbands (termed as pseudospins) around the LLs crossing point. The QHPFs taking place at total filling factor ν = 3, 5 and ν = 4 are easy-plane or easy-axis QHPFs respectively, depending on the details of the two subbands configurations. In spite of various theoretical models [9,10,11] motivated by these findings, a comprehensive understanding is not yet achieved. Thus far, experimental and theoretical studies all focused on the pseudospin freedom. However, in this work we would address the unique spin excitations in the QHPF states.To address the question whether spin states in twosubband systems in nature, measurements other than the conventional transport and optical means are needed. Since the Zeeman energy of nuclear spin is about 3 orders of magnitude smaller than that of electron spin, exchange of spin angular momentum between the electron and nuclear spin is allowed only when the electron system supports spin excitations with low energy. The nuclear spin relaxation rate 1/T 1 thus probes the density of states at low energy of the electron spin system that cannot be accessed by other means. The resistively detected NMR technique has recently emerged as an effective method to probe collective spin states in the fractional quantum Hall regime [12,13], the Skyrmion spin texture close to the filling factor 1 [14,15], the role of electron spin polarization in the phase transition of a bilayer system [16,17], and the ferromagnetic state accompanied by collective spin excitations of a two-subband system [18]. Here we use this technique to study spin freedom and its relation with pseudospin in the vicinity of...