We construct the positive principal series representations for Uq(g R ) where g is of type Bn, Cn, F4 or G2, parametrized by R n where n is the rank of g. We show that under the representations, the generators of the Langlands dual group U q ( L g R ) are related to the generators of Uq(g R ) by the transcendental relations. This gives a new and very simple analytic relation between the Langlands dual pair. We define the modified quantum group U q q (g R ) = Uq(g R ) ⊗ U q ( L g R ) of the modular double and show that the representations of both parts of the modular double commute with each other, and there is an embedding into the q-tori polynomials.