“…When compared with dipole transitions, quadrupole transition rates are typically smaller by a factor ranging from 10 8 in the IR to 10 5 in the optical spectral domain. Such extremely long mean lifetimes against spontaneous emission of quadrupole excitations make them ideal candidates for nextgeneration atomic clocks [6], high-precision tests of molecular physics [7,8,9], and quantum information processing [6,10]. Electric-quadrupole transitions are used for remote sensing of important diatomic molecules, such as hydrogen, oxygen, and nitrogen, in spectra of Earth's atmosphere and other environments [4,11,12].…”