Quantum chemical description of the mechanism of oxidation–reduction copolymerisation between germylene and quinone

Brocławik, Ewa; Bocho-Janiszewska, A.

doi:10.1016/s0166-1280(00)00446-2

Cited by 16 publications

(6 citation statements)

References 8 publications

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“…Since many organic germanium compounds have been found to have biologic activity, [1][2][3][4][5][6] the properties and reactions of germylenes and their derivatives have been well studied. 7,8 Germylenoid is a kind of important derivative of germylene, and may have the stronger stability than germylene.…”

Section: Introductionmentioning

confidence: 99%

Substitution Reactions of the Aluminum Chlorogermylenoid H2GeClAlCl2 with with HF, H2O, NH3, HCl, H2S, and PH3

Yan¹,

Zhang²,

Li³

et al. 2016

ACSi

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Quantum chemical calculations have been performed for the substitution reactions of the aluminum chlorogermylenoid H 2 GeClAlCl 2 with HF, H 2 O, NH 3 , HCl, H 2 S, and PH 3 to get more insights into the reactivity of H 2 GeClAlCl 2 . The theoretical calculated results indicated that the substitution reactions of H 2 GeClAlCl 2 with HF, H 2 O, NH 3 , HCl, H 2 S, and PH 3 proceeded in a concerted manner. There were one transition state and one intermediate which connected the reactants and the products along the potential energy surface. The six substitution reactions of H 2 GeClAlCl 2 with HF, H 2 O, NH 3 , HCl, H 2 S, and PH 3 are compared with the addition reaction s of H 2 Ge with these hydrides. And based on the calculated results we concluded that the substitution reactions of H 2 GeClAlCl 2 with these hydrides involve two steps, one is dissociation onto H 2 Ge with AlCl 3 , and the other is the addition reactions of H 2 Ge with HF, H 2 O, NH 3 , HCl, H 2 S, and PH 3 .

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Section: Introductionmentioning

confidence: 99%

Substitution Reactions of the Aluminum Chlorogermylenoid H2GeClAlCl2 with with HF, H2O, NH3, HCl, H2S, and PH3

Yan¹,

Zhang²,

Li³

et al. 2016

ACSi

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show abstract

“…The research of germanium reaction is an interesting topic since many organic germanium compounds have been found to have biologic activity [1][2][3][4][5][6][7]. The properties and reactions of germylene and its derivatives have been well studied [8,9].…”

Section: Introductionmentioning

confidence: 99%

Theoretical investigation on H2 elimination reactions of germylenoid H2GeLiF with RH (R=F, OH, and NH2)

Liu

Cheng

et al. 2010

Journal of Organometallic Chemistry

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“…Therefore, the research of germanium reactions is an interesting topic since many organic germanium compounds have been found to have biologic activity [21][22][23]. As to the theoretical study of germylenes, some groups have reported the reaction of germylenes with small molecules, such as ethylene [24], quinine [25], oxirane, and thiirane [26]. The relative stabilities of germanitriles and germaimines have been systematically investigated and found that fluorine substitution can dramatically stabilize FGe"N with respect to Ge@NF both from a kinetic and a thermodynamic viewpoint [27].…”

Section: Introductionmentioning

confidence: 99%

Theoretical studies on the imine germylenoid HNGeNaF and its insertion reaction with R–H (R=F, OH, NH2, CH3)

Tan

Wang

et al. 2008

Journal of Organometallic Chemistry

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Quantum chemical description of the mechanism of oxidation–reduction copolymerisation between germylene and quinone

Cited by 16 publications

References 8 publications

Substitution Reactions of the Aluminum Chlorogermylenoid H2GeClAlCl2 with with HF, H2O, NH3, HCl, H2S, and PH3

Substitution Reactions of the Aluminum Chlorogermylenoid H2GeClAlCl2 with with HF, H2O, NH3, HCl, H2S, and PH3

Theoretical investigation on H2 elimination reactions of germylenoid H2GeLiF with RH (R=F, OH, and NH2)

Theoretical studies on the imine germylenoid HNGeNaF and its insertion reaction with R–H (R=F, OH, NH2, CH3)

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