We explain the observation of clusters in the tunneling resonance spectra of small metallic particles of few nanometer size. Each cluster of resonances is identified with one excited single-electron state of the metal particle, shifted as a result of the different nonequilibrium occupancy configurations of the other single-electron states. Assuming the underlying classical dynamics of the electrons to be chaotic, we determine the typical shift to be ∆/g where g is the dimensionless conductance of the grain.An interacting many-body system exhibits, in general, a very complicated behavior. Usually, one can analytically characterize only statistical properties of the spectrum. The fact that, for high enough energies, these properties are very well described by random matrix theory (RMT) [1] was first attributed to the complexity of the many-body system. More recently, it has become clear that RMT also describes single-particle quantum dynamics which is chaotic in the classical limit [2,3]. Examples are non-interacting electrons in small disordered metallic grains [4], and in ballistic quantum dots [5]. Real systems, however, contain a large number of interacting particles, and a question which naturally arises is how does chaos in a single-particle description manifest itself in the properties of the true many-body problem?Experimental [6] as well as theoretical [7,8] studies of this problem, have been mainly focused on two issues: the statistical properties of the ground state energy of quantum dots as the number of electrons changes, and the lifetime of a quasiparticle in such structures. Here we consider the nonequilibrium tunneling resonance spectra of small metallic particles [9]. These spectra can be measured experimentally with high precision [see Figs. 1(a,b)] and interpreted within the Hartree-Fock approximation. They constitute a clear demonstration of the interplay between many-body interactions and quantum chaos, and also provide direct information on the quantum chaotic nature of the system.The experimental system consists of a single aluminum particle connected to external leads via high resistance (1 -5 MΩ) tunnel junctions formed by oxidizing the surface of the particle. In Figs. 1(a,b) we plot the differential conductance, dI/dV , of two different particles (of sizes roughly 2.5 and 4.5 nm) as a function of the source-drain bias energy eV . The spectra display three clear features: