The structural glass transition is often regarded as
purely a problem of the classical theory of liquids. The dynamics
of electrons enters only implicitly, through the interactions between
ionic cores or molecules. Likewise, zero-point effects tied to the
atomic masses hardly affect the typical barriers for liquid rearrangements.
Yet, glasses do exhibit many quantum phenomenaelectronic,
optical, and cryogenic peculiarities that seem to have universal
characteristics. These anomalies of the glassy state are uncommon
or strongly system dependent in crystals and amorphous solids not
made by a quasi-equilibrium quench of a melt. These clearly quantum
phenomena include midgap electronic states in amorphous semiconductors,
the two-level systems, and the Boson peak. Here, we discuss how these
quantum phenomena found in glasses are not merely consequences of
any kind of disorder but have universal characteristics stemming from
the structural dynamics inherent in the glass transition itself. The
quantum dynamics at cryogenic temperatures and electronic dynamics
are related to the transition states for relaxational motions above
the glass transition temperature, which are partially frozen when
the sample is quenched.