In rechargeable batteries, overpotential
problems may occur especially
when the battery is aging. An alarm system to prevent overpotential
may be useful. Colloidal nanoparticles of Fe3O4@SiO2 can self-assemble into amorphous photonic crystals
(APCs) with tunable interparticle distances as a function of applied
voltage. Here, we fabricated a colloidal APC that changes its color
from mahogany to dark blue at applied voltages from 1.0 to 4.0 V,
respectively. Citrate-modified Fe3O4 was solvothermally
synthesized, followed by a SiO2 shell coating by the Stöber
method to achieve a stable APC dispersed in polycarbonate solution.
The APC is then connected alongside a zinc–air battery to indicate
operational events including discharging, charging, and overcharging
by color change of the APC. We anticipate that this simple idea provides
an intuitive way to monitor the status of rechargeable batteries.