Quantitative analysis of heat release during coal oxygen-lean combustion in a O2/CO2/N2 atmosphere by TG-DTG-DSC

Abstract

Heat release of coal combustion in an oxygen-lean and multi-gas environment is a common phenomenon, coalfield fires caused by it can lead to serious environmental destruction and loss of coal resources. Simultaneous thermal analysis experiments for Bulianta (BLT, high-volatile bituminous coal) and Yuwu coal (YW, anthracite) in 21vol.%O2/79vol.%N2 and 15vol.%O2/5vol.%CO2/80vol.%N2 were carried out to study the law of heat release. Based on the TG-DTG-DSC curves, the combustion characteristic parameters were analyzed. Decreasing O2 concentration caused a significant reduction of local reactivity and further the decreasing maximum heat release rate for low-rank coal, while increasing CO2 concentration caused a significant thermal lag effect and further the increasing maximum heat release rate for high-rank coal. The relationship between the heat release rate and the reaction rate constant was quantitatively analyzed. At the increasing stage of the heat release rate, the heat release rate of the two coals increased conforming to ExpGro1 exponential model. At the decreasing stage of the heat release rate, the heat release rate of YW coal decreased exponentially with the reaction rate constant, while the heat release rate of BLT coal decreased linearly. Regardless of the atmospheres, the conversion rates corresponding to maximum heat release rate of BLT and YW coal were about 0.80 and 0.50, respectively, indicating that the coal rank played a dominant role. The results are helpful to understand the heat release process of coal oxygen-lean combustion in O2/CO2/N2.

Experimental Investigation on Gallium and Germanium Migration in Coal Gangue Combustion

“…At this temperature, calcite decomposed into CaO and released CO 2 . Additionally, the presence of the diffraction peak of anorthite was detected in the combustion product at 1000 • C. This observation could be attributed to the decomposition reaction of calcite during the coal gangue combustion process and its interaction with the silica laminate melt, resulting in the formation of anorthite [40,48]. Table 6 presents the contents of Ga and Ge in the combustion products across various particles.…”

“…Calcite decomposes into calcium oxide and carbon dioxide during combustion, potentially affecting the alkalinity of combustion products. The presence of pyrite could influence the migration of sulfur elements in combustion products [39,40].…”

“…The elevated temperatures induced the dehydration and dihydroxylation of clay minerals like kaolinite and illite, promoting the formation of amorphous silicate into a melt. The diffraction peak of kaolinite vanished at 600 • C, while that of illite disappeared at 900 • C, indicating the lower thermal stability of kaolinite compared to that of illite [40,48,49]. Under high-temperature combustion conditions, pyrite particles transformed pyrrhotite because of the intense heat generated during combustion.…”