Quantification of boron in water by of spectrophotometry and thermal lens spectrometry using reaction with beryllon III

Zhirkov, A. A.; Razvazhnaya, O. V.; Казакова, Т. А.; Petrenko, D. B.; Проскурнин, М. А.; Dedkov, Yu. M.; Зуев, Б. К.

doi:10.1134/s106193481109022x

Cited by 6 publications

(4 citation statements)

References 9 publications

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“…Infra-red spectra in the 3400-3200 cm -1 range has an intensive wide band of stretching vibrations ὺ that arise (3) which the experimental data were processed with the help a linear dependence Y = aX + b, where Y is the boron extraction degree, (% -percentage of the boron initial concentration); X is the initial boron concentration in the solution (g/L); a, b are empirical coeffi cients.…”

Section: (Solid)mentioning

confidence: 99%

Chemical modification of cellulose for boron sorption from water solutions

Sarsenov¹,

Бишимбаев²,

Kapsalamov³

et al. 2018

Polish Journal of Chemical Technology

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It is shown that natural cellulose obtained from the walnut shell (Juglans regia) can be used for chemical modifi cation of the selective boron sorbent. The modifi cation was carried out by the coupling technique of chlorine derivatives of the polyhydric alcohols or polyols (mannitol, xylitol, sorbitol or glycerol). In this case new hybrid substances (sorbents) were obtained and they are represented by the formula: R-O-(CHOH) n -CH 3 , where R is a residue of the cellulose backbone, n is the number of functional (OH) groups of the polyhydric alcohols. The pulp mercerization was carried out by processing the ground walnut shell (WS) with hot solution of sodium hydroxide. Chlorination of polyhydric alcohols was carried out by gaseous hydrochloric acid sparging through the polyhydric alcohol aqueous solution. The coupling process proceeds according to the mechanism of substitution of the cellulose hydroxyl groups with chlorine atoms.

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Section: (Solid)mentioning

confidence: 99%

Chemical modification of cellulose for boron sorption from water solutions

Sarsenov¹,

Бишимбаев²,

Kapsalamov³

et al. 2018

Polish Journal of Chemical Technology

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“…TLS is therefore mainly applied as a detection technique for separation methods, like high-performance liquid chromatography (HPLC), capillary electrophoresis (CE), and ion chromatography (IC), which provide the required selectivity. 8,20 However, high specificity can also be introduced into TLS measurements by applying a specific colorimetric reaction, [30][31][32][33] or the concept of bioanalytical assays. [34][35][36] The latter rely on the biorecognition capability of various biomolecules, such as enzymes and antibodies, which react or bind with the analyte with high specificity.…”

Section: Thermal-lens Spectrometry For Fast Screening Approachesmentioning

confidence: 99%

Fast Screening Techniques for Neurotoxigenic Substances and Other Toxicants and Pollutants Based on Thermal Lensing and Microfluidic Chips

et al. 2016

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“…A need to rapidly quantitate tin(II) concentration in an electroless plat ing sensitization solution at concentrations less than 0.3 µg/mL to evaluate its effectiveness motivated the development of the present colorimetric approach. A spectrophotometric approach was selected which complements the existing spectrophotometric meth ods for quantification of boron [9], vanadium(IV) [10], and mercury(II) [11].…”

mentioning

confidence: 99%

Spectrophotometric determination of tin(II) by redox reaction using 3,3′,5,5′-tetramethylbenzidine dihydrochloride and N-bromosuccinimide

2015

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5661 Tin(II) compounds are important in 99m Tc radiop harmaceutical kits as stabilizing agents [1], in dental gels and food as preservatives [2][3][4], and in electroless plating as electrochemical catalysts [5][6][7][8]. Common methods to determine tin(II) are limited by some combination of the range and/or limit of detection, ease of application, reproducibility, and inability to distinguish tin(II) from tin(IV). A need to rapidly quantitate tin(II) concentration in an electroless plat ing sensitization solution at concentrations less than 0.3 µg/mL to evaluate its effectiveness motivated the development of the present colorimetric approach. A spectrophotometric approach was selected which complements the existing spectrophotometric meth ods for quantification of boron [9], vanadium(IV) [10], and mercury(II) [11]. Common methods for determining tin(II) concen tration are summarized in Table 1. These methods are: electrochemistry [1-4, 12-19], membrane sensor [18], inductively coupled plasma-optical emission spectrometry (ICP-OES) [19], flame atomic absorp tion spectrometry (FAAS) [20], fluorescence [21], and spectrophotometry [22-29]. The electrochemi cal method, which includes anodic stripping voltam metry (ASV) [1-4, 12] and differential pulse polarog 1 The article is published in the original.raphy (DPP) [13][14][15][16][17], has been widely used because of selective determination of tin(II) in the presence of tin(IV). The ASV method has a low LOD. For exam ple, a LOD equal to 0.00026 µg/mL was achieved by Hutton et al. by using the ASV method with a bismuth film electrode [3]. However, the limitation of the ASV method is that it requires either formation of a tin(II) complex such as a tin(II)-oxine [1] or a tin(II)-tropolone [2], or use of a modified electrode such as an epoxy carbon electrode or the BiFE [3, 4, 12]. The DPP method does not require a tin(II) complex or a modified electrode but it is limited by the detection range and the LOD. Decristoforo et al. [14] reported a DPP method with a LOD of 0.005 µg/mL but the con centration range was from 10 to 15 µg/mL. Similarly, using the DPP method, Sebastian et al. [15] quantified tin(II) within the concentration range 0 to 10 µg/mL but the LOD was 0.5 µg/mL.Recently published methods based on membrane sensor, ICP, FAAS, and fluorescence quenching im proved the detection concentration range and the LOD, but the constraints in the methods limit their usage. The tin(II) selective potentiometric membrane sensor method was reported to have a concentration range of 0.013 to 1190 µg/mL and a low LOD of 0.0025 µg/mL, but preparation of the membrane elec trode was work intensive [18]. ICP-OES was used to Abstract-A rapid, straightforward spectrophotometric method based on the redox reaction of tin(II) with a mixture of N bromosuccinimide (NBS) and 3,3',5,5' tetramethylbenzidine dihydrochloride (TMB) was developed for determining low concentrations of tin(II). The redox method improved sensitivity by 2.3 fold relative to the existing spectrophotometric methods by t...

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Quantification of boron in water by of spectrophotometry and thermal lens spectrometry using reaction with beryllon III

Cited by 6 publications

References 9 publications

Chemical modification of cellulose for boron sorption from water solutions

Chemical modification of cellulose for boron sorption from water solutions

Fast Screening Techniques for Neurotoxigenic Substances and Other Toxicants and Pollutants Based on Thermal Lensing and Microfluidic Chips

Spectrophotometric determination of tin(II) by redox reaction using 3,3′,5,5′-tetramethylbenzidine dihydrochloride and N-bromosuccinimide

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