The aim of this study was to explore the influence of different barrier and atmosphere conditions on the complex processes affecting storage stability of potato snacks, and the use of oxygen determination measurements within the packaging atmosphere as a quick quality and shelf-life assessment method. The subject of investigation was potato snacks packed in transparent and metallised polymeric packaging laminates, filled with air or nitrogen. Samples were analysed for moisture, water activity, hydroperoxide content and oxygen concentration in the headspace by two methods: a non-invasive optical method based on fluorescence quenching and an electrochemical method. High barrier packaging provides better protection against moisture but not against oxidation. The shelf-life of potato snacks is undermined by oxygen presence in the foam structure of the product. Neither barrier packaging nor modification of atmosphere applied alone bring satisfactory results, therefore a combined strategy is recommended. The study proved that the most optimal solution was the use of metallised packaging with nitrogen. The use of an optical sensor can be an appropriate and effective novel method for a nondestructive oxidation progress evaluation of food that is stored in translucent packaging.Practical applications: The high linear correlation between hydroperoxides and oxygen content is of great practical value in shelf-life assessment and screening the correctness of a packaging process.Abbreviations: ASTM, American society for testing and materials; HSD, honestly significant difference; OTR, oxygen transmission rate; PA, polyamide; PE, polyethylene; PV, peroxide value; WVTR, water vapour transmission rate Eur.