Quadrupole Hyperfine and A1-A2 Splitting in the ν2 Fundamental of Arsine

The ν2/ν4Diad of PH3

“…The same model was already applied to the sub-Doppler enables one to separate the carrier radiation with a grid polarizer which was then used for stabilization on the fluorescence spectrum of the arsine molecule (23). The nuclear spin of phosphorous is 1/2, compared to 3/2 of arsenic, which simemission Lamb dip of CO 2 .…”

Saturation Spectrum of the ν2/ν4Dyad of AsH3

“…In the case of the transitions pP ( 11,6 ) , pP ( 9,6 ) , and r Q ( 13, 9 ) in For the calculation of the rovibrational energy levels we the n 4 fundamental the A 1 -A 2 splitting could be resolved used the matrix elements described in detail in Ref. ( 1). for the first time.…”

“…Thus our spectrometer covers a total fundamental of arsine using saturation spectroscopy ( 1 ) . range of about 60 cm 01 out of the 225 cm 01 between 875 However, because of strong Coriolis coupling between and 1100 cm 01 .…”