This paper investigates the issue of Quality of Experience (QoE) for multimedia services in Internet of Things (IoT), introduces a new concept of "Isomorphism Flow"(iFlow) for multimedia traffic in IoT, which is inspired by abstract algebra based on experimental research and is aggregated from the multimedia traffics with similar Quality of Experience (QoE) requirements for different users, and improves typical QoE evaluation method for multimedia traffic in IoT.Then a new cross-domain QoE guarantee method based on the iFlow QoE is proposed in this paper to adjust the network resource from the perspective of user perception. The proposed scheme is validated through simulation, which indicates the proposed scheme outperforms the current scheme. Specifically, simulation results show that the proposed scheme achieves an enhancement in QoE performance for the multimedia traffics. Furthermore, it retains the perceived QoE of the real-time application users within high satisfaction levels.