Abstract:Herein, we report a new family of covalent organic frameworks (COFs), namely pyrophosphonate-COFs, constructed via pyrophosphonate linkages. Pyrophosphonate-COFs can be synthesized via a single-step condensation reaction of the charge-assisted hydrogen-bonded organic framework (HOF) GTUB5, which is constructed from phenylphosphonic acid and 5,10,15,20‐tetrakis[p‐phenylphosphonic acid] porphyrin. The reported pyrophosphonate-COF, which we call GTUB5-COF was synthesized by simply heating its two-linker HOF precu… Show more
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