Pyrene-based porous organic materials for visible light photocatalysis

Tetrabenzonaphthalene and Redox-Active Anthraquinone-Linked Conjugated Microporous Polymers as Organic Electrodes for Enhanced Energy Storage Efficiency

“…Porous materials play a crucial role across various scientific and technological fields, attracting considerable attention for their potential to enhance functional material design. − conjugated microporous polymers (CMPs) represent a prominent category of organic porous polymers. They are distinguished by their high porosity, lightweight structure, and robust covalent bonds. − As a subset of covalently bonded organic porous materials, CMPs are amorphous and facilitate the conjugated assembly of building blocks within three-dimensional (3D) networks. − CMPs possess distinctive structural characteristics not found in other porous materials, which typically lack π-conjugation, or in conventional conjugated polymers, which are not porous. − CMPs leverage π-conjugated systems, allowing for deliberate modifications to their porous structures, thus enhancing both the framework and its properties. − CMPs can be synthesized through various chemical methods, including the Yamamoto reaction, Friedel–Crafts arylation, cyclotrimerization, Suzuki reaction, Sonogashira–Hagihara reaction, and Schiff base reaction, all of which contribute to the formation of these unique CMPs. − The design of CMPs allows for versatile applications.…”