The Journal of Supercritical Fluids

2016

DOI: 10.1016/j.supflu.2016.06.017

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PVT properties of 1-propanol in the critical and supercritical regions

Ilmutdin M. Abdulagatov

¹

,

А. Р. Базаев

²

,

³

et al.

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Cited by 18 publications

(2 citation statements)

References 165 publications

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“…Chain length increases from left to right. Experimental data are taken from Déak et al, Abdulagatov et al, , Lemmon et al, and Xin et al…”

Section: Resultsmentioning

confidence: 99%

“…Critical loci predictions of the binary mixture of 1propanol with n-butane, n-pentane, n-hexane, n-heptane, n-octane, and n-decane, respectively. Chain length increases from left to right.Experimental data are taken from Deák et al,117 Abdulagatov et al,118,119 Lemmon et al,120 and Xin et al121…”

mentioning

confidence: 99%

See 1 more Smart Citation

Extending the Structural (s)-SAFT-γ Mie Equation of State to Primary Alcohols

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,

²

,

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et al. 2022

Ind. Eng. Chem. Res.

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features a modification to SAFT-γ Mie's chain term, which enables differentiation between the properties of structural isomers. This work now extends structural (s)-SAFT-γ Mie to the (CH 2 OH) functional group in linear primary alcohols. s-SAFT-γ Mie's descriptions of the pure component properties of primary alcohols are either equivalent to or better than those obtained with SAFT-γ Mie. Furthermore, s-SAFT-γ Mie primary alcohol/n-alkane VLE predictions are robust and generally more accurate than those obtained with SAFT-γ Mie. Conversely, SAFT-γ Mie's primary alcohol/n-alkane LLE predictions are more accurate. The differences observed between the models are likely attributable to alternate parametrization strategies employed. Excess enthalpy predictions of both models are qualitatively correct. The s-SAFT-γ Mie CH 2 OH parameters provide a robust foundation for extending the model to other chemical families.

“…Chain length increases from left to right. Experimental data are taken from Déak et al, Abdulagatov et al, , Lemmon et al, and Xin et al…”

Section: Resultsmentioning

confidence: 99%

“…Critical loci predictions of the binary mixture of 1propanol with n-butane, n-pentane, n-hexane, n-heptane, n-octane, and n-decane, respectively. Chain length increases from left to right.Experimental data are taken from Deák et al,117 Abdulagatov et al,118,119 Lemmon et al,120 and Xin et al121…”

mentioning

confidence: 99%

Extending the Structural (s)-SAFT-γ Mie Equation of State to Primary Alcohols

¹

,

²

,

³

et al. 2022

Ind. Eng. Chem. Res.

View full text Add to dashboard Cite

features a modification to SAFT-γ Mie's chain term, which enables differentiation between the properties of structural isomers. This work now extends structural (s)-SAFT-γ Mie to the (CH 2 OH) functional group in linear primary alcohols. s-SAFT-γ Mie's descriptions of the pure component properties of primary alcohols are either equivalent to or better than those obtained with SAFT-γ Mie. Furthermore, s-SAFT-γ Mie primary alcohol/n-alkane VLE predictions are robust and generally more accurate than those obtained with SAFT-γ Mie. Conversely, SAFT-γ Mie's primary alcohol/n-alkane LLE predictions are more accurate. The differences observed between the models are likely attributable to alternate parametrization strategies employed. Excess enthalpy predictions of both models are qualitatively correct. The s-SAFT-γ Mie CH 2 OH parameters provide a robust foundation for extending the model to other chemical families.

Observations regarding the first and second order thermodynamic derivative properties of non-polar and light polar fluids by perturbed chain-SAFT equations of state

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,

²

2019

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No abstract

Molecular dynamics simulation of vapor-liquid equilibrium in 1-alkanol unary systems: a study of surface tension, density, and vapor pressure of TraPPE-UA force field

Jaradat,

Al-Salman,

Obeidat

2024

Fluid Phase Equilibria

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No abstract

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