1955
DOI: 10.1021/ja01606a005
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Puromycin. Synthetic Studies. XI. D-Ribofuranosyl Derivatives of 6-Dimethylaminopurine

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Cited by 75 publications
(34 citation statements)
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“…followed by deacetylation with ammonia-saturated methanol. The tri-0-benzoylribofuranose species I d was similarly obtained from 1-0-acetyl-2,3,5-tri-0-benzoyl-P-D-ribofuranose (17), and 16 was accessible from the reaction of 1-bromo-2,3,5-tri-0-acetylribofuranose (18) with the trimethylsilyl derivative of la, without catalysis by the tin(1V) species.…”
Section: (A) Syntheses and Conversionsmentioning
confidence: 99%
“…followed by deacetylation with ammonia-saturated methanol. The tri-0-benzoylribofuranose species I d was similarly obtained from 1-0-acetyl-2,3,5-tri-0-benzoyl-P-D-ribofuranose (17), and 16 was accessible from the reaction of 1-bromo-2,3,5-tri-0-acetylribofuranose (18) with the trimethylsilyl derivative of la, without catalysis by the tin(1V) species.…”
Section: (A) Syntheses and Conversionsmentioning
confidence: 99%
“…The introduction of 2,3,5-tri-O-benzoyl-n-ribofuranosyl chloride, (6) an apparently more stable activated sugar, furnished higher yields of blocked nucleosides.…”
Section: Synthesis Using Heavy Metal Salls Of Purinesmentioning
confidence: 99%
“…Mercuric salts of thymine or theophylline in inert solvents are generally employed for nucleoside synthesis. [2][3][4][5] The condensation of the salts chloride (1)6) in xylene did not give any of the expected nucleoside; instead, a colorless sirup with no chlorine and nitrogen was obtained. It showed a positive resorcin test (Seliwanoff test),7) a strong band due to an enol acetate, a weak band due to a double bond in the infrared, and an ultraviolet the structure of the product was 2-deoxy-1, 3, 4, 5-tetra-O-acetyl -L-sorbopyranos-2, 3-ene (II) or -1, 2-ene.…”
Section: ) Sorboses Part VIIImentioning
confidence: 99%