The electrodissolution of aluminum electrodes in aqueous solutions containing sulfate or chloride
ions is studied in this work. The results obtained are important in order to obtain a better
understanding of the electrocoagulation process, as the electrodissolution of the anode surface
is its first step. It has been determined that both chemical and electrochemical dissolution play
an important role in the aluminum generation. The chemical dissolution of aluminum is strongly
influenced by the pH. Alkaline pHs increase the dissolution rate by orders of magnitude. Within
the experimental conditions used, the supporting media does not seem to influence greatly the
chemical dissolution process. The electrochemical dissolution process depends mainly on the
specific electrical charge passed. Salinity does not significantly affect the electrodissolution rate.
Good fittings between experimental and modeled data are obtained by modeling the system
with a simple model based on two assumptions: a highly segregated flow pattern and the
calculation of aluminium species and pH from a pseudoequilibrium approach.