Pulsed Atomization and Excitation Sources with Solution Electrodes for Optical Emission Spectroscopy

Yagov, V. V.; Korotkov, A. S.; Zhirkov, A. A.; Зуев, Б. К.

doi:10.1007/978-3-031-09883-3_31

Advances in Geochemistry, Analytical Chemistry, and Planetary Sciences 2023

DOI: 10.1007/978-3-031-09883-3_31

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Pulsed Atomization and Excitation Sources with Solution Electrodes for Optical Emission Spectroscopy

V. V. Yagov

A. S. Korotkov²,

A. A. Zhirkov³

et al.

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Effect of Organic Additives on the Intensity of Metal Lines in the Emission Spectrum of a Drop-Spark Discharge upon Sample Introduction into an Electrolyte Anode

Yagov,

Zhirkov,

Mal’chenkova

2023

Žurnal analitičeskoj himii

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The effect of the nature and concentration of organic medium modifiers on the intensity of lines of some heavy metals (Ag, Cd, Hg, Pb, Tl, Zn) in the spectrum of a drop-spark discharge upon sample introduction into an electrolyte anode is studied. It is shown that additives of 0.1–6 wt % of polar organic compounds greatly increase the intensity of Pb, Tl, and Zn lines and reduce the intensity of Ag lines. The greatest effect, a twenty-fold enhancement of zinc lines, is observed upon the introduction of methanol into dilute acids. The cadmium signal is insensitive to organic impurities in dilute acids, but is enhanced in concentrated salt solutions.

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Effect of Organic Additives on the Intensity of Metal Lines in the Emission Spectrum of a Drop-Spark Discharge upon Sample Introduction into an Electrolyte Anode

Yagov,

Zhirkov,

Mal’chenkova

2023

Žurnal analitičeskoj himii

View full text Add to dashboard Cite

show abstract

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Pulsed Atomization and Excitation Sources with Solution Electrodes for Optical Emission Spectroscopy

Cited by 1 publication

References 24 publications

Effect of Organic Additives on the Intensity of Metal Lines in the Emission Spectrum of a Drop-Spark Discharge upon Sample Introduction into an Electrolyte Anode

Effect of Organic Additives on the Intensity of Metal Lines in the Emission Spectrum of a Drop-Spark Discharge upon Sample Introduction into an Electrolyte Anode

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