“…16 To date, more than 100 MXenes have been experimentally and theoretically predicted, of which up to forty have been prepared (Ti 3 C 2 , Ti 2 C, Mo 2 C, V 2 C, etc.). 17,18 Among them, Ti 3 C 2 T x , the most common MXene material, is more conducive to proton and electron transport in the electrocatalytic CO 2 reduction process because of its excellent electrical conductivity, 19 low energy barrier for electron transport, 20 abundant ionic diffusion pathways, 21 and abundant active sites, 22 which provide necessary prerequisites for CO 2 activation and adsorption of key intermediates. Meanwhile, due to its multilayered lamellar structure and abundant surface end groups (-O, -OH, and -F), it not only increases the possibility of adsorption of CO 2 but also interacts with CO 2 to enhance C-H, C-O, and C-C coupling, which further facilitates the catalytic reaction.…”