Natural-gas leakage from energy-well integrity failure presents a risk to the environment CCA, 2014). Released free-phase "fugitive" gas, comprised primarily of methane (C 1 ), ethane (C 2 ), and propane (C 3 ), tends to migrate vertically due to buoyancy, along two possible pathways toward surface: (a) within or along the surface casing of an energy well (termed surface-casing vent flow, SCVF, or sustained casing pressure depending on if the annulus is shut-in or vented) and/or (b) outside of the well assembly, directly into the natural ground, a process termed gas migration (GM). The release depth, migration patterns, environmental impacts, and fate of GM are highly uncertain and strongly controlled by the subsurface geologic environment. Dissolved fugitive gas from GM can affect water quality if metabolized by microorganisms (Osborn et al., 2011;Vengosh et al., 2014;Woda et al., 2018). A portion of GM-derived fugitive gas may also reach ground surface and emit to the atmosphere as a potent greenhouse gas (Allen et al., 2013;Kang et al., 2016; Saint-Vincent et al., 2020) or accumulate in enclosed spaces of nearby infrastructure, generating an explosion hazard and/or risk of asphyxiation (Chilingar & Endres, 2005;Gorody, 2012).To assess the concerns posed by GM, it is crucial to first understand fugitive-gas migration, distribution, and dissolution in the shallow subsurface. Few studies have investigated these processes, particularly in the field and at relevant scales, therefore our current understanding and ability to assess and predict risks posed Abstract Fugitive natural gas released in the subsurface from leaking oil and gas wells can affect groundwater quality and generate significant greenhouse gas emissions to the atmosphere. We released natural gas into a Western Canada Sedimentary Basin (WCSB) groundwater system located in an area of petroleum resource development. Through 55 depth-discrete monitoring points installed up to 26 m deep, we tracked spatiotemporal evolution of dissolved gases over 760 days. Fugitive gas was diverted and mostly retained in the subsurface by capillary barriers, resulting in highly irregular distribution and dissolution of multicomponent gas constituents. Gas wetness changed significantly during migration, although stable-carbon isotope ratios did not. We expect that where a surface diamict is present, typical of the WCSB, a significant portion of fugitive gas released from leaky wells will be retained in the subsurface, mitigating greenhouse gas emissions to the atmosphere but inferring greater risk on groundwater.
Plain Language SummaryThe impacts of fugitive gas from leaky oil and gas wells remain poorly understood but include greenhouse gas emissions to the atmosphere and degradation of potable groundwater resources. To assess migration patterns, environmental impacts, and fate of fugitive gas, we released natural gas in a shallow groundwater system, representative of much of the Western Canada Sedimentary Basin (WCSB) where extensive petroleum resource development take...