多级孔 Co/Al-SiO 2 催化剂制备及其费-托合成催化性能 王举汉,文雄,刘成超,张煜华,赵燕熹,李金林 (中南民族大学,催化转化与能源材料化学教育部重点实验室和催化材料科学湖北省重点实验室,武汉 430074)
Abstract:Hierarchically porous silica-aluminum is an important support materials for metal-catalysts, because of its excellent properties. Herein, an efficient hydrothermal approach for the production of hierarchical aluminum-doped silica (Al-SiO2) architectures was reported by employing aluminum nitrate as an aluminium source and TEOS as silicon source. The effects of the structure-oriented agent on the structure of Al-SiO2 were investigated.The structural features of Al-SiO2 were characterized by XRD, SEM and N2-physisorption. The results showed that hierarchical Al-SiO2 with "worm-like" porous of 30-40 nm can be synthesized by using TPAOH as the structure-oriented agent and hydrothermal treatment at 80 ℃. The cobalt catalysts were prepared by the wetness impregnation method. Compared with commercial SiO2 supported cobalt catalysts, the Fischer-Tropsch synthesis performance of the catalyst Co/Al-SiO2 is significantly enhanced, i.e., CO conversion nearly doubled, CH4 selectivity reduced by 19.3%, C2-C4 selectivity reduced by 13.3%, and the selectivity of gasoline products (C5-C12) reached 53.3%.