Pseudotetrahedral Organotin-Capped Chalcogenidometalate Supermolecules with Optical Limiting Performance
Ming-Bu Luo,
Heng-Dong Lai,
Shan-Lin Huang
et al.
Abstract:The rational design of crystalline clusters with adjustable compositions and dimensions is highly sought after but quite challenging as it is important to understand their structural evolution processes and to systematically establish structure− property relationships. Herein, a family of organotin-based sulfidometalate supertetrahedral clusters has been prepared via mixed metal and organotin strategies at low temperatures (60−120 °C). By engineering the metal composition, we can effectively control the size o… Show more
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