Proton conduction and phase transitions in orthorhombic N2H6SO4single crystals

Isostrukturelle cucurbiturilbasierte organische poröse Materialien, deren 1D‐Kanäle mit einer Wasser‐Säure‐Anordnung gefüllt sind, unterscheiden sich abhängig von der Art und Menge der in den Kanälen vorliegenden Säuremoleküle in der Protonenleitfähigkeit. Das deutlich anisotrope Leitungsverhalten der Materialien wurde mithilfe von Leitfähigkeitsmessung an Einkristallen untersucht.

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High and Highly Anisotropic Proton Conductivity in Organic Molecular Porous Materials

Yoon

Suh

Kim

et al. 2011

Angewandte Chemie

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High and Highly Anisotropic Proton Conductivity in Organic Molecular Porous Materials

et al. 2011

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Thermally Stimulated Depolarisation Current Studies on Some Hydrogen-Bonded Crystals

Reddy

Sathyanarayan

Sastry

1983

Phys. Stat. Sol. (a)

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Thermally stimulated depolarisation current (TSDC) studies are carried out in three hydrogen‐bonded crystals, namely, (N2H6)SO4, (NH2)3H(SO4), and Li(NH4)SO4. These three crystals are chosen to represent three categories wherein the dipoles are induced by impurities in the crystal, the NH3 dipoles already exist in the crystal, and the crystal possesses inherent dipole moment. TSDC peaks are observed in all the three systems and their activation energies and frequency factors are evaluated. The observed peaks are explained taking into account the nature of impurity–vacancy dipoles and the dipoles inherently present in these systems.

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Proton conduction and phase transitions in orthorhombic N₂H₆SO₄single crystals

Cited by 6 publications

References 13 publications

High and Highly Anisotropic Proton Conductivity in Organic Molecular Porous Materials

High and Highly Anisotropic Proton Conductivity in Organic Molecular Porous Materials

High and Highly Anisotropic Proton Conductivity in Organic Molecular Porous Materials

Thermally Stimulated Depolarisation Current Studies on Some Hydrogen-Bonded Crystals

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