Prospects in the application of a frontally curable epoxy resin for cured‐in‐place‐pipe rehabilitation

Abstract

Photocurable acrylates and vinyl esters are among the most commonly used resins in cured‐in‐place‐pipe (CIPP) rehabilitation technology, as they impart excellent thermomechanical properties in composite pipes. In the quest for achieving a higher energy efficiency of the photo‐curing process in CIPP, the frontal polymerization technique is a viable alternative that requires a lower irradiation dosage coupled with exceptionally high curing speeds and depths. Herein, for the first time, we report the application of frontal polymerization in the rehabilitation of underground pipes using a newly developed frontally curable epoxy‐based resin (Trelleborg Self‐Curing*). The neat resin is characterized for degree of cure, glass transition temperature, and mechanical properties via FTIR, DMA, and tensile tests, respectively. In a comprehensive way, the properties are benchmarked against commercially available acrylate (Trelleborg Light Cure*) and vinyl ester (Trelleborg Rapid Cure*) resins to evaluate their applicability for CIPP. The results show a higher glass transition temperature and final monomer conversion for the frontally cured resin, which cures significantly faster than the reference resins under the same irradiation conditions. In proof‐of‐concept trials, the newly developed resin successfully cures polymeric liners in a PVC host pipe with 100% water tightness and without losing its structural integrity. Results from ring stiffness tests for cured composite pipes additionally show that liners cured with Trelleborg Self‐Curing* resin pass the minimum required Young's modulus for non‐pressure drainage pipes as per ASTM F1216. Thus, frontally curable epoxy‐based resins are a promising and competitive alternative to acrylates and vinyl esters in CIPP.