Property and application of novel ferrocenyl–azobenzene labeled peptide nucleic acid monomers with the dual stimulus–response characteristics

Liu, Sheng; Wang, Jinqing; Li, Jindu; Chen, Miao; Yang, Shengrong

doi:10.1016/j.ica.2009.06.030

Cited by 10 publications

(4 citation statements)

References 20 publications

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“…Liu et al successfully synthesized three novel kinds of peptide nucleic acid (PNA) monomers tagged with ferrocenylazobenzene units. These monomers can be used to detect PNAs themselves by means of UV–visible absorption.…”

Section: Applications Of Ferrocene‐based Derivatives and Polymers Conmentioning

confidence: 99%

Recent research progress in the synthesis, properties and applications of ferrocene‐based derivatives and polymers with azobenzene

Zhai

Wang

et al. 2015

Applied Organom Chemis

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Aromatic azobenzene derivatives are outstanding organic photochromic compounds that possess unique photochemical properties. These compounds are widely used in research and development for various applications, especially in information storage, owing to their ability to isomerize between cis (Z) and trans (E) forms under the influence of light of different wavelengths. On account of these advantages, many efforts have been made to generalize the use of azobenzene derivatives. Furthermore, ferrocene-based polymers and derivatives are promising candidates for functional materials due to their unique redox properties. By interlinking ferrocene with azobenzene, novel functional materials can be obtained that will integrate the excellent properties of both and will provide new applications in various fields including information storage, ion recognition, molecular devices, etc. This article provides an overview of the synthesis, properties and applications of novel ferrocene-based polymers and derivatives containing azobenzene units.

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Section: Applications Of Ferrocene‐based Derivatives and Polymers Conmentioning

confidence: 99%

Recent research progress in the synthesis, properties and applications of ferrocene‐based derivatives and polymers with azobenzene

Zhai

Wang

et al. 2015

Applied Organom Chemis

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“…27 Featured with easy synthesis and photochromic characteristics, azocarbazole compounds have a wide range of applications in textile fiber dyeing, optical conversion and image storage, holography and other fields. [37][38][39][40][41][42] What's more, carbazoles are extensively studied as dyes for photopolymerization. 43 Due to the larger conjugated system, the absorption wavelength of azocarbazole compounds generally reaches the visible light region, suggesting that the azocarbazole photosensitive skeleton could be used to construct a unimolecular visible light initiator.…”

Section: Introductionmentioning

confidence: 99%

A class of azocarbazole‐based carboxylates: High‐efficiency ionic unimolecular photobase generators for thiol‐epoxy click polymerization under blue light

Xiong

et al. 2021

Journal of Polymer Science

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Two new unimolecular azocarbazole-based visible photobase generators (Ac-C-Base) with different strong bases such as 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and 1,1,3,3-tetramethylguanidine (TMG) as the potential active species were prepared. Their structures were confirmed by 1 H NMR, 13 C NMR, and HR-MS. According to the photolysis and EPR results, Ac-C-Base could generate free radicals and strong bases simultaneously through the photodecarboxylation mechanism under 455 nm LED irradiation. Thus they can effectively catalyze the thiol-epoxy polymerization without post exposure baking under light exposure. In addition, the Ac-C-TBD containing a stronger base shows a faster polymerization rate and higher epoxy conversion.

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“…These complexes with different structures exhibit diverse spectral characteristics and functionality depending on the arene ligand. Moreover, azo compounds have drawn considerable attention because of their applications in photoelectronics, printing systems, optical storage technology, and photochemistry [24][25][26][27]. Azo compounds, which are connected to organometallic compounds in their structures, possess the properties of both organometallic and azo groups; thus, these compounds can be utilized to produce materials with interesting magnetic, electronic, optic, and anisotropic properties [28][29][30].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and optical properties of a D–A–D cationic cyclopentadienyl iron complex containing double arylazo chromophores

Liu

Jia

Li³

et al. 2014

Res Chem Intermed

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A D-A-D cationic cyclopentadienyl iron complex containing double arylazo chromophores (Fc-diazo) with methoxyl group (Fc-diazo-OMe) was obtained via nucleophilic substitution and well characterized by IR, UV-visible, 1 H NMR, and 13 C NMR spectroscopy, and MS. UV-Vis absorption and nonlinear optical property of Fc-diazo-OMe were investigated by comparison of Fc-diazo with no methoxyl group (Fc-diazo-H). Quantum chemical calculations of the orbital energy, geometric structure of Fc-diazo-OMe, and Fc-diazo-H were conducted by using density functional methods at the B3PW91/Lanl2dz level. Charge transfer from the highest occupied molecular orbital to the lowest unoccupied molecular orbital was found based on density functional theory. The substitution of the methoxyl group greatly improves the NLO property of Fc-diazo. Fc-diazo-OMe shows effective two-photon absorption, coefficient and third-order nonlinear susceptibility for potential applications as optical materials, while Fc-diazo-H barely shows NLO ability.

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Property and application of novel ferrocenyl–azobenzene labeled peptide nucleic acid monomers with the dual stimulus–response characteristics

Cited by 10 publications

References 20 publications

Recent research progress in the synthesis, properties and applications of ferrocene‐based derivatives and polymers with azobenzene

Recent research progress in the synthesis, properties and applications of ferrocene‐based derivatives and polymers with azobenzene

A class of azocarbazole‐based carboxylates: High‐efficiency ionic unimolecular photobase generators for thiol‐epoxy click polymerization under blue light

Synthesis and optical properties of a D–A–D cationic cyclopentadienyl iron complex containing double arylazo chromophores

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