Proceedings of the Unified International Technical Conference on Refractories (UNITECR 2013) 2014
DOI: 10.1002/9781118837009.ch91
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Properties of Self‐Glazing Al 2 O 3 ‐C‐Refractories Influenced by the Graphite Content and Nanoscaled Additives

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“…The EDX result revealed that these nano phases with bamboo-like shapes, as shown in the inset of Figure 3B, were carbon fibers derived from the residual phenolic resin 16 . 22 As already reported in the literature, 11,20,[23][24][25] the introduction of nano carbons into Al 2 O 3 -C refractories can help to develop whiskers. However, SiC phase detected in the XRD pattern at 1200°C was not clearly observed in the matrix by SEM, which might be located inside the network of carbon fibers.…”
Section: Phases and Microstructure Evolutionmentioning
confidence: 84%
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“…The EDX result revealed that these nano phases with bamboo-like shapes, as shown in the inset of Figure 3B, were carbon fibers derived from the residual phenolic resin 16 . 22 As already reported in the literature, 11,20,[23][24][25] the introduction of nano carbons into Al 2 O 3 -C refractories can help to develop whiskers. However, SiC phase detected in the XRD pattern at 1200°C was not clearly observed in the matrix by SEM, which might be located inside the network of carbon fibers.…”
Section: Phases and Microstructure Evolutionmentioning
confidence: 84%
“…The pyrolysis of resin and the shortage of in situ formed ceramic bonding phases were responsible for the low strengths. 22 The CMOR of the low carbon Al 2 O 3 -C refractory increased rapidly with temperature. 11,12,24 Ludwig et al found that the whiskers network also plays a role in the mechanical strength.…”
Section: Mechanical Properties and Thermal Shock Resistancementioning
confidence: 97%