We investigated the assignments and characteristics of the X-ray-induced colour centres in a silver-activated radiophotoluminescent glass. The inducedabsorption spectrum was decomposed into six Gaussian bands, which were, in turn, attributed to the Ag + , Ag 3 + or Ag 3 2+ , Ag 2 + , Ag 2+ , Ag 0 and hole-trap centres, respectively, by means of optical and thermal measurements. All components of the blue and orange radiophotoluminescence (RPL) in a silver-activated phosphate glass were confirmed to be X-ray-induced colour centres. We also proposed and constructed a new readout system for the measurement of the RPL of the glass dosimeter that considers the characteristics of the radiation-induced bands.