New halogen-containing oligoethers based on 1,1-hydroxy-2,2-di (4-hydroxyphenyl) ethylene and 1,1-dichloro-2,2-di (4-hydroxyphenyl) ethylene of various degrees of condensation were synthesized by the method of high-temperature polycondensation. Features are investigated and optimal conditions of synthesis of new oligoethers are defined. On the basis of polysulfone compositions with various maintenance of oligoethers are prepared. With usage of the modern methods of researches, it is shown that new composites surpass industrial polysulfone in the main physical and chemical and production characteristics.