“…Therefore, it indicates that the Fe3O4 particles can succeed to form a core formation shell with SiO2 as a layer [1,18,40,41].The stretching and bending vibration of the H-O-H bond are found at wave numbers of 1641-3465 cm -1 . Such functional groups have almost similar characteristics with the Fe3O4@a-SiO2 particles obtained from the references [27], [28]. Figure 3b.…”
Section: Resultssupporting
confidence: 71%
“…Typically, the SiO2 nanoparticle has an amorphous phase, and it can be commercially produced as silica gel, fume-silica, and so forth. Several applications of SiO2 nanoparticles for examples such as medical purposes [22][23][24], as additives for rubber and plastics [25][26][27], as fillers for composite construction concrete [28][29][30], as stabilizers and agents drug delivery and theranostics [23,31], and as a heavy metal absorbent material in a water filter [14], [22].…”
This article reports the results synthesis of crystalline (Fe3O4@c-SiO2) and amorphous (Fe3O4@a-SiO2) nanoparticles from natural resources (iron sand and silica sand). The synthesis of Fe3O4 and SiO2 nanoparticles used co-precipitation and hydrothermalcoprecipitation methods with polyethylene glycol (PEG) 4000 as a template. The XRD data analysis presented that the amorphous SiO2 particles were successfully produced using hydrothermal and co-precipitation methods. The XRD data analysis also presented that the crystalline phases were formed in quartz and tridymite phases after calcination process of the amorphous phase. SEM images exhibited that the amorphous phase had different particle size and morphology from the crystalline phase. FTIR spectra presented some absorption peaks of new functional groups indicating the existence of Si-O-Si (silanol), Fe-O, C-N, and Fe-O-Si as new functional groups.
“…Therefore, it indicates that the Fe3O4 particles can succeed to form a core formation shell with SiO2 as a layer [1,18,40,41].The stretching and bending vibration of the H-O-H bond are found at wave numbers of 1641-3465 cm -1 . Such functional groups have almost similar characteristics with the Fe3O4@a-SiO2 particles obtained from the references [27], [28]. Figure 3b.…”
Section: Resultssupporting
confidence: 71%
“…Typically, the SiO2 nanoparticle has an amorphous phase, and it can be commercially produced as silica gel, fume-silica, and so forth. Several applications of SiO2 nanoparticles for examples such as medical purposes [22][23][24], as additives for rubber and plastics [25][26][27], as fillers for composite construction concrete [28][29][30], as stabilizers and agents drug delivery and theranostics [23,31], and as a heavy metal absorbent material in a water filter [14], [22].…”
This article reports the results synthesis of crystalline (Fe3O4@c-SiO2) and amorphous (Fe3O4@a-SiO2) nanoparticles from natural resources (iron sand and silica sand). The synthesis of Fe3O4 and SiO2 nanoparticles used co-precipitation and hydrothermalcoprecipitation methods with polyethylene glycol (PEG) 4000 as a template. The XRD data analysis presented that the amorphous SiO2 particles were successfully produced using hydrothermal and co-precipitation methods. The XRD data analysis also presented that the crystalline phases were formed in quartz and tridymite phases after calcination process of the amorphous phase. SEM images exhibited that the amorphous phase had different particle size and morphology from the crystalline phase. FTIR spectra presented some absorption peaks of new functional groups indicating the existence of Si-O-Si (silanol), Fe-O, C-N, and Fe-O-Si as new functional groups.
“…For instance, compared to the control specimens without Ns (C-S and CG-BP) and irrespective of the type of fibers included, the compressive strength of the NFRM increased by up to 168% and 108% at three days for mixtures without and with slag, respectively. These results are consistent with the effect of nano-silica on cementitious systems, which effectively contributes to the strength development of cement-based materials through multiple mechanisms, including accelerated pozzolanic activity [15][16][17][18][19][20][21][22], filler effect [20,21], and water absorption into the high surface area of silica particles/agglomerates (i.e., reduction of w/b in the paste) [21]. In addition, the results of the NFRM at 28 and 56 days indicated that there was continuous and significant improvement in strength beyond seven days in comparison to the fiber reinforced mortars without nano-silica, especially for mixtures containing slag.…”
Repair and rehabilitation of deteriorating concrete elements are of significant concern in many infrastructural facilities and remain a challenging task. Concerted research efforts are needed to develop repair materials that are sustainable, durable, and cost-effective. Research data show that fiber-reinforced mortars/concretes have superior performance in terms of volume stability and toughness. In addition, it has been recently reported that nano-silica particles can generally improve the mechanical and durability properties of cement-based systems. Thus, there has been a growing interest in the use of nano-modified fiber-reinforced cementitious composites/mortars (NFRM) in repair and rehabilitation applications of concrete structures. The current study investigates various mechanical and durability properties of nano-modified mortar containing different types of fibers (steel, basalt, and hybrid (basalt and polypropylene)), in terms of compressive and flexural strengths, toughness, drying shrinkage, penetrability, and resistance to salt-frost scaling. The results highlight the overall effectiveness of the NFRM owing to the synergistic effects of nano-silica and fibers.
“…ese nanoparticles can result in a dense ITZ through two mechanisms: one is physical and the other one is chemical. e latter is attributed to the chemical ability of the SiO 2 nanoparticles to react with the Ca(OH) 2 (one of the cement hydration products) and leading to the formation of more gel product, calcium silicate hydroxide (C-S-H), which is the product responsible of the strength of the concrete and dense microstructure of the ITZ in concrete [23,39,40]. e former can be due to large surface area and the super-ultrafine size of the nanoparticles.…”
Section: Concrete Specimensmentioning
confidence: 99%
“…e former can be due to large surface area and the super-ultrafine size of the nanoparticles. is small size of these particles helps in filling up all the micropores/nanopores and voids exit in the attached mortar and the ITZ resulting in a more densified microstructure of the cement matrix [34,38,40]. Hence, these two mechanisms seem to be the main reasons behind the improvement of the strength of the RAC containing nanoparticles of SiO 2 .…”
e aim of this paper was to examine the feasibility of using nanoparticles of SiO 2 (nanosilica) to improve the performance of recycled aggregate concrete (RAC) containing recycled aggregate (RA) derived from processing construction and demolition waste of concrete buildings. e examined properties include compressive strength, splitting tensile strength, and water absorption. e study also includes examining the microstructure of RA and RAC with and without nanoparticles of SiO 2 . In total, nine mixes were investigated. Two mixes with RA contents of 50% and 100% were investigated and for each RA content; three mixes were prepared with three different nanoparticles dosages 0.4%, 0.8%, and 1.2% (by mass of cement). A control mix with natural aggregate (NA) was also prepared for comparison reasons. e results show that nanoparticles of silica can improve the compressive strength, tensile strength, reduce the water absorption, and modify the microstructure of RAC.
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