“…53 All these minerals are rare, with the exception of kermesite, which is described in notable quantities in many localities. The second group of "modular" minerals includes minerals of the valleriite group [valleriite, (Fe 2+ ,Cu) 4 (Mg,Al) 3 S 4 (OH,O) 6 , 54 tochilinite, Fe 2+ 5−6 (Mg,Fe 2+ ) 5 S 6 (OH) 10 , 55 haapalaite, (Fe 2+ ,Ni) 2 (Mg,Fe 2+ ) 1.61 S 2 (OH) 3.22 , 56 yushkinite, (Mg,Al)-V 4+ S 2 (OH) 2 , 57,58 as well as vyalsovite, FeCaAlS(OH) 5 , 59,60 and bazhenovite, Ca 8 S 2 (S 3 )( 61 (the study by Bindi et al 62 demonstrated that bazhenovite does not contain thiosulfate groups, and therefore, its crystalchemical formula should be corrected). It should be noted that bazhenovite was discovered, described, and approved as a valid mineral species from the burned dumps of the ChCB.…”