“…The sensitivity of the spectroscopy is limited by backgrounds from uncorrelated laser light scatter, photomultiplier dark or radiation-induced counts and light from fast ion collisions with residual-gas molecules. All but the latter can be reduced by, i), coincidence detection of the fluorescent ion [96] or, ii), bunched delivery of ionic ensembles [127]. Non-optical detection of excitations, those not involving the observation of scattered photons, can be realised by virtue of optical pumping combined with stateselective neutralisation [69] or re-ionisation [35,36].…”