Properties and Uses of Thallium

Howe, H. E.; Smith, Aaron

doi:10.1149/1.2778000

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1954

2001

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“…Atmospheric attack on thallium is relatively slow (1), the observed initial penetration rate being 2-10u/day depending on the aggressiveness of the environment.…”

Section: Introductionmentioning

confidence: 99%

Reaction of Thallium with Oxygen and Moisture

Waber

Sturdy

1954

J. Electrochem. Soc.

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Reactions of thallium with water vapor and air were investigated in the range 25~176 to throw light on the mechanism of atmospheric corrosion. It was deduced on the basis of changes in the rate laws, and confirmed by x-ray diffraction, that the principal reaction product changes from T120 to T1OH as the relative humidity of air increases. Parabolic and cubic laws, as well as a new growth law, were observed. Effects of carbon dioxide and of preformed sulfide films were also studied. The tentative x-ray structure of T1OH is presented.

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“…Atmospheric attack on thallium is relatively slow (1), the observed initial penetration rate being 2-10u/day depending on the aggressiveness of the environment.…”

Section: Introductionmentioning

confidence: 99%