Abstract:We evaluated dialkylsulfonium salts with an aromatic cyclic ketone structure (a 1-indanone, 1-tetralone, or 4-chromanone unit) as a photoacid generator for ArF chemically amplified resists. The thermal stability of the salts was affected by alkyl subsitituents. Sulfonium salts with two methyl groups or a pentamethylene group exhibited a decomposition temperature of more than 200 °C. The absorption coefficients at 193 nm for the new PAGs were 1/3 to 1/4 that of the conventional triphenylsulfonium salt. The phot… Show more
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