Propellanes. 16. Bridgehead olefin formation via 11,11-dihalo[4.4.1]propellane solvolysis

Abstract

Die Propellane (I) werden der Hydrolyse in verschiedenen Wasser‐Aceton‐Gemischen unterworfen.

Propellanes. 17. Bridgehead olefins via solvolysis of 10,10-dibromo[4.3.1]propellanes

“…-319(11) H(6') 036 (8) 307 (8) 029 (11) "The heavy atom positional and thermal parameters are X 104. The hydrogen atom positional parameters are X 103; all hydrogen atoms were refined with fixed isotropic thermal parameters'^= 4.0.…”

“…38 The remaining nonhydrogen atoms were located by successive structure factor39 and electron density map calculations. 38 Approximate positions for the aromatic and methylene hydrogens were cal- -0070 (8) 4178( 6) 2668( 1) 69 (10) 3K5)…”

“…192 (19) -0(6) 34( 11) 5( 7) 0 (2) -0280( 10) 2627( 6) 3121( 13) 130( 12) 30(5) 23K21) -6 (7) 70 (13) -6(9) 0(3) 3958( 9) 2732( 8) 1475( 13) 85( 10) 55( 6) 194( 20) 19( 8) 24 (12) -13(9) 0(1) 3488 (12) 3526( 8) 2307( 16) 65( 13) 28( 8) 147( 22) 12( 8) 19( 14) 9(9) 0 (2) 4193 (15) 4358 (11) 1647( 22) 62( 16) 50( 10) 261(36) -9(10) 20( 19) 9 (15) 0(3) 3900( 19) 5328( 14) 2208( 27) 120( 28) 50( 12) 205 (31) -12 (13) 14( 23) 1( 15) 0(4) 2810 (17) 5674 (10) 2598 (19) 104 (20) 19 (8) 206 (30) -3…”

“…H(8b) 329( 7) 318( 10) 328( 15 -034 (10) 264( 17) H(14a) 043( 7) 598( 10) 538( 16) H(14b) 054 (7) 698(H) 427 (15) H (14c) -023 (8) 630 (9) 377 (15) "The heavy atom positional and thermal parameters are X 104. The hydrogen atom positional parameters are X 103; all hydrogen atoms were refined with fixed isotropic thermal parameters5¡^= 4.5.…”