The absolute triply differential cross section for relativistic electron-impact ionization of the 2p 3/2 subshell of gold has been measured in an (e, 2e) coincidence experiment as a function of the scattering angle of the outgoing slow electrons. A primary electron energy of 300 keV, coplanar asymmetric geometry and kinematical conditions to match the bound-electron Bethe ridge have been chosen. The agreement with theoretical results obtained in the relativistic distorted-wave Born approximation is good, while the discrepancies with the semirelativistic Coulomb-Born approximation are somewhat larger.