Production of phenolic-rich bio-oil from catalytic fast pyrolysis of biomass using magnetic solid base catalyst

Zhang, Zhibo; Lü, Qiang; Ye, Xiaoning; Li, Wentao; Hu, Bin; Chen, Dong

doi:10.1016/j.enconman.2015.10.063

Cited by 72 publications

(26 citation statements)

References 56 publications

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“…The detected dominant compounds are phenolics and hydrocarbons including monocyclic aromatic (peaks5,7,12,[17][18] and naphthalene compounds (peaks16,[19][20], with slight acids (peak 14), ketones (peaks 1-3) and furans (peak 9) compounds. This result indicated that the Fe/Ca x O catalysts in this work possessed the capability of inhibiting the devolatilization of holocellulose to form organic volatiles, and meanwhile, promoting the decomposition of lignin to form phenolics[29]. With the increase of Fe load in the Fe/Ca x O catalyst, the total peak area, representing the total product yield decreased gradually.…”

mentioning

confidence: 76%

Stoichiometric synthesis of Fe/Ca x O catalysts from tailored layered double hydroxide precursors for syngas production and tar removal in biomass gasification

Zhang

Yang

Xie

et al. 2016

Journal of Analytical and Applied Pyrolysis

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mentioning

confidence: 76%

Stoichiometric synthesis of Fe/Ca x O catalysts from tailored layered double hydroxide precursors for syngas production and tar removal in biomass gasification

Zhang

Yang

Xie

et al. 2016

Journal of Analytical and Applied Pyrolysis

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“…03 wt% respectively; by contrast, the gas yield increased to 42.08 wt%. As reported [35,36], pyrolysis temperature and catalyst direct the pyrolysis reactions to deoxygenate the organic compounds of bio-oils, consequently improving the fuel and chemical qualities of bio-oils. Fig.…”

Section: Effects Of Pyrolysis Temperatures On Product Yields Of the Cmentioning

confidence: 94%

Catalytic pyrolysis of oil palm mesocarp fibre on a zeolite derived from low-cost oil palm ash

Khanday

Kabir

Hameed

2016

Energy Conversion and Management

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“…Others investigated activated carbon as a catalyst on the catalytic microwave pyrolysis of palm kennel shells for phenol production [289]. Zhang et al [290] reported the use of a magnetic solid base catalyst (potassium phosphate ferroferioxide) for catalyst fast pyrolysis of popular wood species to selectively produce phenolic-rich bio-oil. Kim et al [287] investigated the effect of alcohol solvents (ethanol, methanol, and propanol) and catalyst types on the physic-chemical properties of lignin-oil (obtained from depolymerization of Asian lignin).…”

Section: Lignin As Feedstockmentioning

confidence: 99%

Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries

2019

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The production of chemicals from biomass, a renewable feedstock, is highly desirable in replacing petrochemicals to make biorefineries more economical. The best approach to compete with fossil-based refineries is the upgradation of biomass in integrated biorefineries. The integrated biorefineries employed various biomass feedstocks and conversion technologies to produce biofuels and bio-based chemicals. Bio-based chemicals can help to replace a large fraction of industrial chemicals and materials from fossil resources. Biomass-derived chemicals, such as 5-hydroxymethylfurfural (5-HMF), levulinic acid, furfurals, sugar alcohols, lactic acid, succinic acid, and phenols, are considered platform chemicals. These platform chemicals can be further used for the production of a variety of important chemicals on an industrial scale. However, current industrial production relies on relatively old and inefficient strategies and low production yields, which have decreased their competitiveness with fossil-based alternatives. The aim of the presented review is to provide a survey of past and current strategies used to achieve a sustainable conversion of biomass to platform chemicals. This review provides an overview of the chemicals obtained, based on the major components of lignocellulosic biomass, sugars, and lignin. First, important platform chemicals derived from the catalytic conversion of biomass were outlined. Later, the targeted chemicals that can be potentially manufactured from the starting or platform materials were discussed in detail. Despite significant advances, however, low yields, complex multistep synthesis processes, difficulties in purification, high costs, and the deactivation of catalysts are still hurdles for large-scale competitive biorefineries. These challenges could be overcome by single-step catalytic conversions using highly efficient and selective catalysts and exploring purification and separation technologies.

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Production of phenolic-rich bio-oil from catalytic fast pyrolysis of biomass using magnetic solid base catalyst

Cited by 72 publications

References 56 publications

Stoichiometric synthesis of Fe/Ca x O catalysts from tailored layered double hydroxide precursors for syngas production and tar removal in biomass gasification

Stoichiometric synthesis of Fe/Ca x O catalysts from tailored layered double hydroxide precursors for syngas production and tar removal in biomass gasification

Catalytic pyrolysis of oil palm mesocarp fibre on a zeolite derived from low-cost oil palm ash

Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries

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