Abstract:Conditions for the reduction of titaniummagnetite concentrates (main components are Fe 52-54 % and TiO 2 5-7 %) by natural gas for obtaining iron powder and titanium fraction were studied. Based on the theory of granulation in the drum apparatus, granules with 25 % of soda fluxing additive with optimum diameter, humidity, strength and porosity were obtained. It was found that the reduction reactions in the temperature range of 1143-1198 K are carried out if a mixture of hydrogen and carbon monoxide is added to… Show more
“…Owing to the depletion of rich magnetite ore reserves, the research has been developed on technology of titanium ore processing to produce iron, titanium, chromium and vanadium [1][2][3][4]. To determine optimal conditions of oxidation-reduction reactions, thermodynamic calculations are widely used [5][6][7][8].…”
Non-equilibrium and equilibrium thermodynamic conditions of direct reduction of magnetite to free iron and oxidation of vanadium (3) to vanadium (5) in granules fluxed by soda vanadist titanomagnetite concentrates using a mixture of natural gas and hydrogen were determined. To determine temperature dependences of Gibbs free energy of redox reactions, the Temkin-Schwartsman equation was modified with due regard for the Gibbs free energy of formation of magnetite-based substitution solid solutions and the vapor pressure of the components in the flow system where the mixture of methane and hydrogen is continuously fed while gaseous reaction products are removed. 3D modeling of the Gibbs free energy difference of reactions proceeding under equilibrium and non-equilibrium conditions was carried out. On the basis of the free energy of the system deviation from the equilibrium state, it revealed that the greatest effect of reducing the temperature of redox reactions is observed in terms of low values of the reaction products pressure As a result of the thermodynamic analysis, the temperature range of 950-970K was chosen to produce metallic iron and sodium vanadate.
“…Owing to the depletion of rich magnetite ore reserves, the research has been developed on technology of titanium ore processing to produce iron, titanium, chromium and vanadium [1][2][3][4]. To determine optimal conditions of oxidation-reduction reactions, thermodynamic calculations are widely used [5][6][7][8].…”
Non-equilibrium and equilibrium thermodynamic conditions of direct reduction of magnetite to free iron and oxidation of vanadium (3) to vanadium (5) in granules fluxed by soda vanadist titanomagnetite concentrates using a mixture of natural gas and hydrogen were determined. To determine temperature dependences of Gibbs free energy of redox reactions, the Temkin-Schwartsman equation was modified with due regard for the Gibbs free energy of formation of magnetite-based substitution solid solutions and the vapor pressure of the components in the flow system where the mixture of methane and hydrogen is continuously fed while gaseous reaction products are removed. 3D modeling of the Gibbs free energy difference of reactions proceeding under equilibrium and non-equilibrium conditions was carried out. On the basis of the free energy of the system deviation from the equilibrium state, it revealed that the greatest effect of reducing the temperature of redox reactions is observed in terms of low values of the reaction products pressure As a result of the thermodynamic analysis, the temperature range of 950-970K was chosen to produce metallic iron and sodium vanadate.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.