Original techniques were proposed for calculating and optimizing double cascades (DC) built of square cascades and a square cascade with an additional product flow (SCAP). Both cascade schemes (DC and SCAP) were tested in solving a task of simultaneous enrichment of three components of a model mixture to a pre-defined level. A comparison of the DC and SCAP efficiency was made according to the minimum of total cascade flow. The results have shown that the double cascade is more efficient in terms of the chosen criterion.