A zerodur mirror whose aperture is 900mm is chosen to be the primary mirror of an optical system. The mirror is polished by rapid polishing and precision polishing methods relatively. The final surface figures of the mirror are as follows: the peak-to-valley value (P-V value) is 0.204λ (λ=632.8nm), and the root-mean-square value (RMS value) is 0.016λ, which meet the requirement of the optical system. The results show that the polishing process is feasible.With the rapid development of modern optical remote sensing, new requirements such as large field of view, high resolution and high signal-to-noise ratio are proposed to the optical system. Therefore, large-apertured aspheric mirror is applied widely as the primary mirror of optical system. The choice of the materials of the mirror is very important to the performance of the optical system. Proper mirror materials should have excellent physical properties as follows, high stiffness, low density, low coefficient of thermal expansion, high coefficient of thermal conductivity, good processability for optical manufacturing, excellent stability, and etc.. Low density means that the mass of both the mirror and its supporting structure are low. High ratio of stiffness to density means that we can get excellent mechanical performance, i.e. the deformation of the mirror caused by load is so low that the mirror has better performance to resist the stress of polishing, assemblage and self-weight. Low coefficient of thermal expansion means that the structure dimension of the mirror changes less. High coefficient of thermal conductivity means that the mirror is easy to maintain the surface figure which is designed.The standard mirror materials are as follow, silicon carbide (SiC), beryllium (Be), ultra-low-expansion glass (ULE), zerodur, fused silica, K9 glass and etc. [1] . The properties of the materials are listed in Table 1. From the table, it can be seen that Be has the most excellent mechanical performance, it not only has the highest coefficient of thermal expansion, but also is poisonous, which restricts its application. The mechanical performance of SiC is excellent, but it has relative high coefficient of thermal expansion, and it is more difficult to manufacture than ULE, Zerodur, fused silica and K9 glass. The stability of fused silica is not good. The coefficient of thermal expansion of K9 glass is high while its Young's modulus is low. ULE and zerodur are the better materials for their excellent thermal stability and processability. Therefore, ULE and zerodur have large field of application for their relative mature processing and optical manufacturing technologyies. Since zerodur has better mechanical properties and is easier to obtain than ULE, the choice of zerodur is reasonable. Table 1 Properties of the standard mirror materials Type of materials Density (Kg/m 3 ) Young's modulus (Gpa) Ratio of stiffness to density(GNmKg -1 ) Poisson's ratio Coefficient of thermal expansion (10 -6 K -1 ) Coefficient of thermal conductivity (Wm -1 K -1 ) SiC 3080 350 0.11 0...