Production of 5-hydroxymethylfurfural from glucose catalyzed by hydroxyapatite supported chromium chloride

Zhang, Zehui; Zhao, Zongbao K.

doi:10.1016/j.biortech.2010.11.098

Cited by 82 publications

(49 citation statements)

References 13 publications

(13 reference statements)

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“…Niobic acid, niobium phosphate, vanadium phosphate, sulfated zirconia, Amberlyst-15 and acid-functionalized mesoporous silica were also found to exhibit high activity for the fructose dehydration [34][35][36][37][38][39][40]. Moreover, the use of solid acids in ionic liquid was examined [41][42][43][44][45][46][47][48].…”

Section: Synthesis Of 5-hydroxymethylfurfural From Fructose and Glucomentioning

confidence: 99%

Catalytic Transformations of Biomass-Derived Materials into Value-Added Chemicals

2012

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This manuscript reviews recent literatures on synthesis of furfurals (5-hydroxymethylfurfural, furfural, 5-methyl-2-furaldehyde) from various sugars (glucose, fructose, D-galactose, D-arabinose, xylose, L-rhamnose, lactose, cellobiose, sucrose) and furfural conversions into other carbonyl compounds (2,5-diformylfuran, 2,5-furandicarboxylic acid, levulinic acid, succinic acid) using catalytic methodology. Our recent achievements on one-pot synthesis of furfurals using solid acid and base catalysts and selective oxidations of furfurals using heterogeneous catalysts are also included.

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Section: Synthesis Of 5-hydroxymethylfurfural From Fructose and Glucomentioning

confidence: 99%

Catalytic Transformations of Biomass-Derived Materials into Value-Added Chemicals

2012

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“…Therefore, there is tremendous interest to develop new processes not only for fuels but also as a starting material for our chemical industry from cellulose. Hydrolysis of cellulose is considered to be an entry point of biorefinery schemes, as the resulting glucose can be further converted into various chemicals and biofuels [6]. However, the poor solubility of cellulose limited this process.…”

Section: Introductionmentioning

confidence: 99%

Efficient acid-catalyzed hydrolysis of cellulose in organic electrolyte solutions

Zhang

Liu

Zhao

2012

Polymer Degradation and Stability

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“…Niobic acid, niobium phosphate, vanadium phosphate, sulfated zirconia, Amberlyst-15, and acid-functionalized mesoporous silicas are also found to exhibit high catalytic activity for fructose dehydration [161][162][163][164][165][166][167]. Moreover, solid acid catalysts have also been examined in ionic liquids [168][169][170][171][172][173][174][175].…”

Section: Synthesis Of 5-hydroxymethylfurfural From Fructose and Glucomentioning

confidence: 99%

Mechanistic Studies of Solid Acids and Base‐Catalyzed Clean Technologies

Takagaki

Nishimura

Ebitani

2013

Heterogeneous Catalysts for Clean Technology

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IntroductionThe importance of solid acid and base catalysts in clean technologies has been recognized for a long time, and many books and reviews have been published since the text by Tanabe [1]. Tanabe et al.[2] revised their book in 1989, reviewing the definition and classification of solid acids and bases, determination of acidic and basic properties, and catalysis for isomerization, acylation, hydration of alkenes, methanol conversion, dehydration, dehydrogenation, esterification, hydrolysis, hydrocraking (hydrogenolysis), and oxidation reactions. The development of solid acid catalysts has been surveyed in several reviews [3][4][5][6][7][8][9][10]. Catalysis by solid bases and the mechanism of base-catalyzed reactions such as isomerization of alkenes and alkynes, aldol addition and aldol condensation, Henry reaction (nitro-aldol reaction), Knoevenagel condensation, Michael addition, the Tishchenko reaction, alkylation reactions, and addition reactions such as addition of amines to epoxides, transfer hydrogenation (Meerwein-Ponndorf-Verley (MPV) reaction), esterification and transesterification, and liquid-phase oxidations including Baeyer-Villiger oxidation and alkene epoxidation have been recently emphasized by Ono and Hattori [11], encompassing many splendid reviews and papers [12][13][14][15][16][17][18][19][20].The first part of this chapter is intended to survey recent literature on new catalytic materials because the development of new types of metal oxides and layered-and carbon-based materials with different morphologies opens up novel acid-base catalysis that enables new type of clean reaction technologies. Mechanistic considerations of acid-and base-catalyzed reactions should result in new clean catalytic processes for Green and Sustainable Chemistry, for example, transformations of biorenewable feedstock into value-added chemicals and fuels [21][22][23][24][25][26][27][28][29][30][31][32][33][34][35]. The latter part of this chapter, therefore, focuses on biomass conversion using solid acid and base catalysts, which covers recent developments on acid-base, one-pot reaction systems for carbon-carbon bond formations, and biomass conversion including synthesis of furfurals from sugars, biodiesel production, and glycerol utilization.

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Production of 5-hydroxymethylfurfural from glucose catalyzed by hydroxyapatite supported chromium chloride

Cited by 82 publications

References 13 publications

Catalytic Transformations of Biomass-Derived Materials into Value-Added Chemicals

Catalytic Transformations of Biomass-Derived Materials into Value-Added Chemicals

Efficient acid-catalyzed hydrolysis of cellulose in organic electrolyte solutions

Mechanistic Studies of Solid Acids and Base‐Catalyzed Clean Technologies

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