Production of 1,3-butadiene in one step catalytic dehydration of 2,3-butanediol

Nguyen, Ngoc-Khanh; Matei-Rutkovska, F.; Huchede, M.; Jaillardon, Karine; Qingyi, G.; Michel, Carine; Millet, J.M.M.

doi:10.1016/j.cattod.2018.07.007

Cited by 29 publications

(33 citation statements)

References 16 publications

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“…The high activity of Ce@MOR is attributed to the high density of Brønsted acid sites with medium strength. Nguyena et al [59] reported the dehydration of 2,3-BDO Figure 2. Synthesis of BD from ethanol.…”

Section: Catalysts 2018 8 X For Peer Review 3 Of 25mentioning

confidence: 99%

“…The high activity of Ce@MOR is attributed to the high density of Brønsted acid sites with medium strength. Nguyena et al [59] reported the dehydration of 2,3-BDO to BD over a GdPO 4 catalyst which resulted in the complete conversion of 2,3-BDO and a selectivity of 58% to BD at 300 • C. Both the fresh and regenerated GdPO 4 displayed relatively stable catalytic activity in a 50 h run. Kim et al [60] carried out the direct dehydration of 2,3-BDO over silica-supported sodium phosphates catalysts at 400 • C. These findings show that the conversion of 2,3-BDO can be easily tuned up to 100%, while the selectivity to BD never exceeds 70%.…”

Section: Catalysts 2018 8 X For Peer Review 3 Of 25mentioning

confidence: 99%

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Synthesis of 1,3-Butadiene and Its 2-Substituted Monomers for Synthetic Rubbers

Liu

et al. 2019

Catalysts

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Synthetic rubbers fabricated from 1,3-butadiene (BD) and its substituted monomers have been extensively used in tires, toughened plastics, and many other products owing to the easy polymerization/copolymerization of these monomers and the high stability of the resulting material in manufacturing operations and large-scale productions. The need for synthetic rubbers with increased environmental friendliness or endurance in harsh environments has motivated remarkable progress in the synthesis of BD and its substituted monomers in recent years. We review these developments with an emphasis on the reactive routes, the products, and the synthetic strategies with a scaling potential. We present reagents that are primarily from bio-derivatives, including ethanol, C4 alcohols, unsaturated alcohols, and tetrahydrofuran; the major products of BD and isoprene; and the by-products, activities, and selectivity of the reaction. Different catalyst systems are also compared. Further, substituted monomers with rigid, polar, or sterically repulsive groups, the purpose of which is to enhance thermal, mechanical, and interface properties, are also exhaustively reviewed. The synthetic strategies using BD and its substituted monomers have great potential to satisfy the increasing demand for better-performing synthetic rubbers at the laboratory scale; the laboratory-scale results are promising, but a big gap still exists between current progress and large scalability.

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Section: Catalysts 2018 8 X For Peer Review 3 Of 25mentioning

confidence: 99%

Section: Catalysts 2018 8 X For Peer Review 3 Of 25mentioning

confidence: 99%

Synthesis of 1,3-Butadiene and Its 2-Substituted Monomers for Synthetic Rubbers

Liu

et al. 2019

Catalysts

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“…2,3‐BDO esterification with malic acid results in Polyurethane‐meliamides (PUMAs), which are useful for cardiovascular applications. Another commercial product (1,3‐butadiene) is used extensively in rubber production and can be obtained by the dehydration of bio‐derived 2,3‐BDO 8,9 . Several other applications of 1,3‐butadiene include as a solvent for resins and lacquers, antifreeze agent, octane booster analytical reagent, as well as in cosmetics, perfumery, 10 printing inks, 11 as a plasticizer, 12 and in the synthesis of various pharmaceutical derivatives 13‐16 .…”

Section: Introductionmentioning

confidence: 99%

Bioglycerol (C3) upgrading to 2,3‐butanediol (C4) by cell‐free extracts of Enterobacter aerogenes NCIM 2695

Parate

Borgave

Dharne

et al. 2021

J of Chemical Tech & Biotech

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BACKGROUND Production of biobased chemicals from renewable resources is a green starring approach that serves as a substitute to petroleum derivatives. Bioglycerol, with its growing production as a co‐product of biodiesel, is an attractive low‐cost feedstock for the synthesis of platform chemicals by microbial fermentation. 2,3‐butanediol (2,3‐BDO) is amongst the top biorefinery platform chemicals that can be produced by glycerol fermentation. RESULTS The ‘Circular Economy’ concept is demonstrated by converting the by‐product bioglycerol using a cell‐free extract of Enterobacter aerogenes NCIM 2695 (National Collection of Industrial Microorganisms, NCIM), yielding 22 g L−1 2,3‐BDO, in 96 h, 98% atom economy and 0.4 g/g E factor. The cell‐free bioglycerol conversion to 2,3‐BDO was proved using a modified procedure for determining glycerol dehydrogenase enzyme assay by protein analysis and it was also shown to be cell‐bounded. CONCLUSION Our study offers an effective utilization of the leftover material (i.e. cell‐free extract) that biocatalysed C3 to C4 diol, which adds value to the overall economics of the process using only crude glycerol (C3) itself as a fermentative medium. © 2020 Society of Chemical Industry

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“…2,3-BD (2,3-butanediol), as well as some derivatives, are employed in plastic and solvent production, such as octane booster in fuels, antifreeze agent or analytical reagent in the racemic separation of carbonyl compounds for gas chromatography [1,2]. One of the main applications of 2,3-BD is its conversion to 1,3-butadiene, employed in synthetic rubber production [3]. Dyacetil, the dehydrogenation product of 2,3-BD, is a highly-valued flavor and bacteriostatic agent for the food industry.…”

Section: Introductionmentioning

confidence: 99%

Improved Raoultella planticola Strains for the Production of 2,3-Butanediol from Glycerol

et al. 2019

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Raw glycerol is an industrial byproduct from biodiesel production and is one of the most promising substrates for 2,3-butanediol (2,3-BD) production; however, 2,3-BD is not yet produced by fermentation from glycerol on a commercial scale due to poor process economics. Class 1 microorganism collections were screened and Raoultella planticola strain CECT 843 proved to be the best 2,3-BD producer, achieving (23.3 ± 1.4) g 2,3-BD per L and a yield of 36% (g 2,3-BD per g glycerol). To further increase product concentration and yield, R. planticola CEC T843 was subjected to random mutagenesis using ultra-violet (UV) light and ethyl methane sulfonate (EMS). Two mutant strains were found to produce at least 30% more 2,3-BD than the wild type: R. planticola IA1 [(30.8 ± 3.9) g 2,3-BD per L and 49% yield] and R. planticola IIIA3 [(30.5 ± 0.4) g 2,3-BD per L and 49% yield].

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Production of 1,3-butadiene in one step catalytic dehydration of 2,3-butanediol

Cited by 29 publications

References 16 publications

Synthesis of 1,3-Butadiene and Its 2-Substituted Monomers for Synthetic Rubbers

Synthesis of 1,3-Butadiene and Its 2-Substituted Monomers for Synthetic Rubbers

Bioglycerol (C3) upgrading to 2,3‐butanediol (C4) by cell‐free extracts of Enterobacter aerogenes NCIM 2695

Improved Raoultella planticola Strains for the Production of 2,3-Butanediol from Glycerol

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