Production and Application of Polymer Foams Employing Supercritical Carbon Dioxide

Abstract

Polymeric foams have characteristics that make them attractive for different applications. However, some foaming methods rely on chemicals that are not environmentally friendly. One of the possibilities to tackle the environmental issue is to utilize supercritical carbon dioxide ScCO2 since it is a “green” solvent, thus facilitating a sustainable method of producing foams. ScCO2 is nontoxic, chemically inert, and soluble in molten plastic. It can act as a plasticizer, decreasing the viscosity of polymers according to temperature and pressure. Most foam processes can benefit from ScCO2 since the methods rely on nucleation, growth, and expansion mechanisms. Process considerations such as pretreatment, temperature, pressure, pressure drop, and diffusion time are relevant parameters for foaming. Other variables such as additives, fillers, and chain extenders also play a role in the foaming process. This review highlights the morphology, performance, and features of the foam produced with ScCO2, considering relevant aspects of replacing or introducing a novel foam. Recent findings related to foaming assisted by ScCO2 and how processing parameters influence the foam product are addressed. In addition, we discuss possible applications where foams have significant benefits. This review shows the recent progress and possibilities of ScCO2 in processing polymer foams.

Synthesis of High-Value Bio-Based Polyamide 12,36 Microcellular Foams with Excellent Dimensional Stability and Shape Recovery Properties

“…General techniques for fabricating PA foams comprise extrusion foaming, injection molding foaming, bead foaming, and microcellular supercritical carbon dioxide foaming (scCO 2 ). Among these foaming techniques, based on the need for ecological safety, PA foams made using the scCO 2 foaming method are encouraged [ 12 , 13 ]. Compared with conventional blowing agents such as chlorofluorocarbons and alkanes, scCO 2 is green, inflammable, nonhazardous, and solvable in polymer matrix [ 14 ].…”