“…represent the largest family of intermetallic compounds having attractive attributes for elevated-temperature mechanical and environmental properties and, hence, are well recognized as a new family of highand/or ultrahigh-temperature candidate structural materials, because of their excellent combinations of high melting point, low density, high elastic modulus, and excellent oxidation resistance. [1][2][3][4][5][6][7][8][9][10][11][12] From a tribological point of view, these silicidebased intermetallic alloys also have excellent tribological properties (e.g., abrasive and adhesive wear resistance as well as a low coefficient of friction, due to their intrinsic roomand high-temperature high hardness and their unique covalent-dominated intermetallic atomic-bonding characteristics) and are, therefore, a new class of promising advanced wearresistant candidate materials for tribological components working under corrosive and high-temperature hostile service conditions. [13][14][15][16][17][18] However, like most intermetallic alloys, the existence of intrinsic room-temperature brittleness and lack of adequate strength and creep resistance at elevated temperatures are currently the main obstacles that prevented the materials from industrial applications as either structural or tribological bulk components.…”