2008
DOI: 10.1007/s00397-007-0243-2
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Processing and characterization of biodegradable polymer nanocomposites: detection of dispersion state

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Cited by 34 publications
(22 citation statements)
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“…The mixing condition used, was barrel temperature of 170 8C, blade speed of 65 min À1 , and time of mixing of 30 min for all samples. At the beginning of the mixing, a high resistance to rotation of the mixer blades was noted which was also observed in the former studies [22]. As the time passed, the torque of the mixer started to decrease and became stable after some time.…”
Section: Experimental Procedures 21 Materialssupporting
confidence: 75%
“…The mixing condition used, was barrel temperature of 170 8C, blade speed of 65 min À1 , and time of mixing of 30 min for all samples. At the beginning of the mixing, a high resistance to rotation of the mixer blades was noted which was also observed in the former studies [22]. As the time passed, the torque of the mixer started to decrease and became stable after some time.…”
Section: Experimental Procedures 21 Materialssupporting
confidence: 75%
“…For example, the M n of PHBV was reduced to 68% of the value for the starting polymer when processing in the mini‐extruder but only to 92% of this value when processing in the internal mixer. This finding may be due to the higher thermal impact on the polymer when processing in the mini‐extruder 14. Changing from air to a flow of nitrogen in the mini‐extruder did not significantly influence PHBV degradation when processing without clay.…”
Section: Resultsmentioning
confidence: 89%
“…This finding may be due to the higher thermal impact on the polymer when processing in the mini-extruder. 14 Changing from air to a flow of nitrogen in the mini-extruder did not significantly influence PHBV degradation when processing without clay. However, when blending with Cloisite20A, PHBV degradation was to some extent determined by whether processing occurred under air or nitrogen.…”
Section: Effect Of Processing Methods and Conditions On The Degradatiomentioning
confidence: 83%
“…A similar twin-screw mixer has been also used by Pogodina et al (2008) to determine the shear rate and viscosity from batch mixer data. They found out that when the binder and metallic powders are introduced in the mixing chamber, it offers a certain resistance to the blades rotation and therefore the torque increases.…”
Section: Powder Bindersmentioning
confidence: 99%