Probing the effect of substituents and solvent on [Mn(R-sal-N-1,5,8,12)]BPh4: a systematic investigation of SCO properties
Chun-Yan Qin,
Sen-Yu Zhang,
Hao-Ze Zhang
et al.
Abstract:The non-covalent interactions and magneto-structural properties of complexes 1–5 are tuned by modifying the solvents and different substituents at the 5-position or 3,5-positions on the phenyl rings of the salicylaldehyde.
Three novel Mn(iii) vanhd complexes, namely [Mn(o-vanhd)(N3−)(H2O)]·CH3OH (1), [Mn(o-vanhd)(NCS−)(H2O)]·2CH3CN (2), and [Mn(o-vanhd)(H2O)]·ClO4·H2O (3), have been successfully synthesized using compartmental ligands paired with ancillary ligands.
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