This paper is a theoretical report on a resonant photon emission process assisted by surface plasmons in the charge-exchange scattering of ions at a metal surface. Slow protons, for example, moving parallel to the surface induce an image charge. A proton and the image charge form an electric dipole at the boundary. When a proton captures a surface electron, the dipole vanishes rapidly, and this necessarily results in a photon emission in accordance with classical electrodynamics. We calculate the photon emission probability in a semiclassical way on the basis of a boundary value problem for a radiation field converted from a surface plasmon excited by the inelastic tunneling current of an electron. Photons with the same frequency as the surface plasmon are emitted dominantly, provided that the energy conservation law is satisfied. The probability is estimated at approximately 0.001 for one collision, which is ϳ10 4 larger than that of the direct photon emission process caused by the inelastic tunneling current.