The thermochemical conversion process
of solid fuels is explicitly
shown as the processes of pyrolysis (including coking and carbonization),
gasification, and combustion. These processes actually involve a similar
complex reaction network. The so-called “decoupling”
refers to the optimization approach of process performance through
controlling the interactions between or among the involved individual
reactions. Our previous article in Energy & Fuels (2010, 24, 6223–6232) has analyzed
how the approach of decoupling applies to the gasification technologies
and justified the realized effects from decoupling. This successive
report is devoted to understanding the applications of decoupling
to the other types of thermochemical conversion technologies (mainly
including pyrolysis and combustion) so as to generalize the “decoupling”
methodology for innovations of thermochemical conversion technologies.
After a reiteration of the principle and implementation approaches
(isolating and staging) for decoupling, reanalysis of the process
design principle and its consequent technical superiorities based
on decoupling is performed for a few well-known or emerging novel
conversion technologies developed in the world. The concrete technologies
exemplified and their realized beneficial effects include the high-efficiency
advanced coal coking processes with moisture control or gentle pyrolysis
of feedstock in advance, coal pyrolysis in multiple countercurrent
reactors for producing high-quality tar, gasification of caking coal
in fluidized bed through adopting jetting preoxidation of coal, low-NO
x
decoupling combustion of coal by developing
the in-bed NO
x
reduction capabilities
of pyrolysis gas and char, and coal topping combustion for the coproduction
of tar and heat. These highlights further justified that the decoupling
would be a viable technical choice for achieving one or more of the
technical advantages among polygeneration, high efficiency, high product
quality, wide fuel adaptability, low pollutant emissions in thermochemical
conversions of solid carbonaceous fuels.